Ok now that you got that going...forgive me if I'm not 100% exact on some of this, I'm doing most of it from memory.
Lets remove some of the auto settings. Set the following:
HTT X4
FSB 201 (yes, 201, not 200, there's a reason for this)
CPU Multi X9
CPU Voltage 1.4
MEM Voltage 2.6 (MIGHT need 2.65)
PCI Clock 33.33 MHZ
Disable PEG Link
Do not ever turn on Cool n Quiet, should be disabled
As for the memory timings, you'll want to run CPUz and use the values for CAS Latency, RAS to CAS Delay, RAS Precharge, Cycle Time and CPC (Command per clock). Hopefully you got 2 DIMMS only, in which case you can run CPC at 1T, otherwise you have to run at 2T. BTW, what memory did you get?
From the BIOS, just enable the Marvel NIC.
As for the drivers, you'll want to use the NVidia RAID controller. The Si one can only be used in a RAID configuration. ASUS removed the ability to use the Si in non raid some time ago for some reason. So you'll need to put the drivers on disk for the windows install, press F6. BTW, hope you got some new SATA drives with NCQ. I grabbed 2 Seagates and mirrored them. They fly

When you get Windows loaded, you'll want to update the NVidia chipset drivers first. ASUS recommends that you do this before updating the BIOS. I believe they are on version 77.77 or somewhere around there now. Do not install the NVidia firewall, network management, or their IDE S/W drivers. It should just be the Bus Management or something like that. Tell me the options you get if you are not sure. After you reboot, go ahead and update the BIOS. I believe the current one is around 1007. ASUS has a BIOS update program so you can do this in Windows. After this you can install the video drivers. As for the other drivers, just install them directly from the CD. I just explorered the CD and went straight to the Marvel drivers and the Audio drivers (if you are using the onboard audio). Once you do all this, you are pretty much done. You may want to download the latest ASUS Probe and NVidia nTune (I just use it to check the GPU temp) If you made the BIOS changes that I said, nTune should not report any error on startup. Oh, BTW, you will need to reset the BIOS settings after you update it. I believe the program will clear the settings. It may have an option to turn it off, let it clear it. If after you do this it's acting weird, just reset the BIOS and reconfigure with the settings I gave you. You may want to run Prime95 and 3DMark05 (there are other programs as well, but this should be ok for now) for several hours just to burn it in and make sure it's stable.
Once you are confident that everything is fine, you can OC it. I can help you out with that as well. Never enable that ASUS auto OCing or use nTune to OC it. Your system will turn to crap and just crash.
If you want to read up on OCing yourself, I recommend
http://www.ocforums.com. They have stuff broken down all the way to MB manufacturers. For example
http://www.ocforums.com/forumdisplay.php?f=44
BTW, some people have had issues with this MB (I did), but others haven't. For example, 2 of my friends bought the same MB and CPU. Neither had a problem. I happened to get a bad MB so I sent it back for replacement. I should have it back by the end of the week, I hope. After I sent it back, I read that either my memory voltage was too low or the heat pipe wasn't making proper contact with the chipset. I heard of someone just taking it apart, removing the paste with alchohol and putting that arctic ceramic stuff himself. After he did that it stopped crashing.
When the world is mine, your death shall be quick and painless.